Polymer surface patterning via Diels-Alder trapping of photo-generated thioaldehydes

Glassner, M., Oehlenschlaeger, K. K., Welle, A., Bruns, M., & Barner-Kowollik, C. (2013) Polymer surface patterning via Diels-Alder trapping of photo-generated thioaldehydes. Chemical Communications, 49(6).

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Abstract

An efficient method for polymer surface patterning via Diels-Alder trapping of photo-generated thioaldehydes is presented. It is demonstrated that thioaldehyde end-groups generated by photolysis of phenacyl sulfides can be quantitatively trapped with various dienes. Poly(ethylene glycol) is immobilized on a surface in a spatially controlled fashion via irradiation through a shadow mask. © 2013 The Royal Society of Chemistry.

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31 citations in Scopus
32 citations in Web of Science®
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ID Code: 99346
Item Type: Journal Article
Refereed: Yes
Additional Information: Cited By :30
Export Date: 5 September 2016
CODEN: CHCOF
Correspondence Address: Barner-Kowollik, C.; Preparative Macromolecular Chemistry, Institut für Technische Chemie und Polymerchemie, Karlsruhe Institute of Technology (KIT), Engesserstraße 18, 76128 Karlsruhe, Germany; email: christopher.barner-kowollik@kit.edu
Chemicals/CAS: macrogol, 25322-68-3; Aldehydes; Polyethylene Glycols; Polymers; Sulfides
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Keywords: macrogol, phenacyl sulfide, polymer, thioaldehyde, unclassified drug, article, Diels Alder reaction, irradiation, photolysis, surface property, Aldehydes, Click Chemistry, Cycloaddition Reaction, Light, Polyethylene Glycols, Polymers, Sulfides, Surface Properties
DOI: 10.1039/c2cc37651b
ISSN: 13597345
Divisions: Current > Schools > School of Chemistry, Physics & Mechanical Engineering
Current > Institutes > Institute for Future Environments
Current > QUT Faculties and Divisions > Science & Engineering Faculty
Deposited On: 22 Sep 2016 04:50
Last Modified: 29 Sep 2016 22:17

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