Polymer surface patterning via Diels-Alder trapping of photo-generated thioaldehydes

Glassner, M., Oehlenschlaeger, K. K., Welle, A., Bruns, M., & Barner-Kowollik, C. (2013) Polymer surface patterning via Diels-Alder trapping of photo-generated thioaldehydes. Chemical Communications, 49(6).

View at publisher


An efficient method for polymer surface patterning via Diels-Alder trapping of photo-generated thioaldehydes is presented. It is demonstrated that thioaldehyde end-groups generated by photolysis of phenacyl sulfides can be quantitatively trapped with various dienes. Poly(ethylene glycol) is immobilized on a surface in a spatially controlled fashion via irradiation through a shadow mask. © 2013 The Royal Society of Chemistry.

Impact and interest:

31 citations in Scopus
32 citations in Web of Science®
Search Google Scholar™

Citation counts are sourced monthly from Scopus and Web of Science® citation databases.

These databases contain citations from different subsets of available publications and different time periods and thus the citation count from each is usually different. Some works are not in either database and no count is displayed. Scopus includes citations from articles published in 1996 onwards, and Web of Science® generally from 1980 onwards.

Citations counts from the Google Scholar™ indexing service can be viewed at the linked Google Scholar™ search.

ID Code: 99346
Item Type: Journal Article
Refereed: Yes
Additional Information: Cited By :30
Export Date: 5 September 2016
Correspondence Address: Barner-Kowollik, C.; Preparative Macromolecular Chemistry, Institut für Technische Chemie und Polymerchemie, Karlsruhe Institute of Technology (KIT), Engesserstraße 18, 76128 Karlsruhe, Germany; email: christopher.barner-kowollik@kit.edu
Chemicals/CAS: macrogol, 25322-68-3; Aldehydes; Polyethylene Glycols; Polymers; Sulfides
References: Carroll, G., Wang, D., Turro, N., Koberstein, J., (2008) Glycoconjugate J., 25, p. 5; Blawas, A.S., Reichert, W.M., (1998) Biomaterials, 19, p. 595; Ganesan, R., Yoo, S.Y., Choi, J.-H., Lee, S.Y., Kim, J.-B., (2008) J. Mater. Chem., 18, p. 703; Pauloehrl, T., Delaittre, G., Winkler, V., Welle, A., Bruns, M., Börner, H.G., Greiner, A.M., Barner-Kowollik, C., (2012) Angew. Chem., Int. Ed., 51, p. 1071; Deforest, C.A., Polizzotti, B.D., Anseth, K.S., (2009) Nat. Mater., 8, p. 659; Jonkheijm, P., Weinrich, D., Köhn, M., Engelkamp, H., Christianen, P.C.M., Kuhlmann, J., Maan, J.C., Waldmann, H., (2008) Angew. Chem., Int. Ed., 47, p. 4421; Norberg, O., Lee, I.H., Aastrup, T., Yan, M., Ramström, O., (2012) Biosens. Bioelectron., 34, p. 51; Hensarling, R.M., Doughty, V.A., Chan, J.W., Patton, D.L., (2009) J. Am. Chem. Soc., 131, p. 14673; Adzima, B.J., Tao, Y., Kloxin, C.J., Deforest, C.A., Anseth, K.S., Bowman, C.N., (2011) Nat. Chem., 3, p. 258; Orski, S.V., Poloukhtine, A.A., Arumugam, S., Mao, L., Popik, V.V., Locklin, J., (2010) J. Am. Chem. Soc., 132, p. 11024; Dietrich, M., Delaittre, G., Blinco, J.P., Inglis, A.J., Bruns, M., Barner-Kowollik, C., (2012) Adv. Funct. Mater., 22, p. 304; Pauloehrl, T., Delaittre, G., Bruns, M., Meißler, M., Börner, H.G., Bastmeyer, M., Barner-Kowollik, C., (2012) Angew. Chem., Int. Ed., 51, p. 9181; Arumugam, S., Orski, S.V., Locklin, J., Popik, V.V., (2012) J. Am. Chem. Soc., 134, p. 179; Gruendling, T., Oehlenschlaeger, K.K., Frick, E., Glassner, M., Schmid, C., Barner-Kowollik, C., (2011) Macromol. Rapid Commun., 32, p. 807; Glassner, M., Oehlenschlaeger, K.K., Gruendling, T., Barner-Kowollik, C., (2011) Macromolecules, 44, p. 4681; Inglis, A.J., Sinnwell, S., Stenzel, M.H., Barner-Kowollik, C., (2009) Angew. Chem., Int. Ed., 48, p. 2411; Glassner, M., Delaittre, G., Kaupp, M., Blinco, J.P., Barner-Kowollik, C., (2012) J. Am. Chem. Soc., 134, p. 7274; Vedejs, E., Eberlein, T.H., Varie, D.L., (1982) J. Am. Chem. Soc., 104, p. 1445; Vedejs, E., Eberlein, T.H., Mazur, D.J., McClure, C.K., Perry, D.A., Ruggeri, R., Schwartz, E., Varie, D.L., (1986) J. Org. Chem., 51, p. 1556; Vedejs, E., Reid, J.G., (1984) J. Am. Chem. Soc., 106, p. 4617; Wilde, R.G., Billheimer, J.T., Germain, S.J., Hausner, E.A., Meunier, P.C., Munzer, D.A., Stoltenborg, J.K., Wexler, R.R., (1996) Bioorg. Med. Chem., 4, p. 1493; Lock, E.H., Petrovykh, D.Y., MacK, P., Carney, T., White, R.G., Walton, S.G., Fernsler, R.F., (2010) Langmuir, 26, p. 8857; Engin, S., Trouillet, V., Franz, C.M., Welle, A., Bruns, M., Wedlich, D., (2010) Langmuir, 26, p. 6097; Benninghoven, A., (1994) Angew. Chem., Int. Ed. Engl., 33, p. 1023
Keywords: macrogol, phenacyl sulfide, polymer, thioaldehyde, unclassified drug, article, Diels Alder reaction, irradiation, photolysis, surface property, Aldehydes, Click Chemistry, Cycloaddition Reaction, Light, Polyethylene Glycols, Polymers, Sulfides, Surface Properties
DOI: 10.1039/c2cc37651b
ISSN: 13597345
Divisions: Current > Schools > School of Chemistry, Physics & Mechanical Engineering
Current > Institutes > Institute for Future Environments
Current > QUT Faculties and Divisions > Science & Engineering Faculty
Deposited On: 22 Sep 2016 04:50
Last Modified: 29 Sep 2016 22:17

Export: EndNote | Dublin Core | BibTeX

Repository Staff Only: item control page