Investigating Cu(0)-Mediated Polymerizations: New Kinetic Insights Based on a Comparison of Kinetic Modeling with Experimental Data

Haehnel, A. P., Fleischmann, S., Hesse, P., Hungenberg, K. D., & Barner-Kowollik, C. (2013) Investigating Cu(0)-Mediated Polymerizations: New Kinetic Insights Based on a Comparison of Kinetic Modeling with Experimental Data. Macromolecular Reaction Engineering, 7(1).

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Abstract

A kinetic model is developed mimicking experimental results obtained via detailed kinetic investigation of Cu0-mediated LRP processes of butyl acrylate in variable solvents at 50°C. In all polymerizations, a pronounced offset in the M̄n versus conversion profile is observed. The kinetic modeling predicts that conventional FRP is responsible for a high molecular weight fraction of terminated polymer. The initial M̄n offset is congruent with a relatively slow establishment of the controlling equilibrium. Kinetic modeling and experiments demonstrate that the conversion versus time data cannot be adequately described by a first-order kinetic analysis. For selected rate coefficients (ka, kd, and kdis_cu) a range is assigned, which affords a well controlled polymerization. © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

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ID Code: 99349
Item Type: Journal Article
Refereed: Yes
Additional Information: Cited By :13
Export Date: 5 September 2016
Correspondence Address: Barner-Kowollik, C.; Preparative Macromolecular Chemistry, Institut für Technische Chemie und Polymerchemie, Karlsruhe Institute of Technology (KIT), Engesserstr. 18, 76128 Karlsruhe, Germany; email: christopher.barner-kowollik@kit.edu
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Keywords: Computer modeling, Kinetics (polym.), Polyacrylates, Single-electron-transfer living-radical polymerization, Solvent polarity variation, Butyl acrylates, Controlled polymerization, Detailed kinetics, First order kinetics, High molecular weight, Kinetic modeling, Kinetic models, Kinetics(polym.), Rate coefficients, Solvent polarity, Data handling, Kinetic theory, Polymerization, Solvents, Kinetics
DOI: 10.1002/mren.201200030
ISSN: 1862832X
Divisions: Current > Schools > School of Chemistry, Physics & Mechanical Engineering
Current > Institutes > Institute for Future Environments
Current > QUT Faculties and Divisions > Science & Engineering Faculty
Deposited On: 22 Sep 2016 04:50
Last Modified: 30 Sep 2016 00:20

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