Visual recognition of supramolecular graft polymer formation via phenolphthalein-cyclodextrin association

Hetzer, M., Fleischmann, C., Schmidt, B. V. K. J., Barner-Kowollik, C., & Ritter, H. (2013) Visual recognition of supramolecular graft polymer formation via phenolphthalein-cyclodextrin association. Polymer (United Kingdom), 54(19).

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Visual recognition of the formation of supramolecular graft polymers in aqueous solution driven by host-guest assembly is presented. The interaction between β-cyclodextrin (β-CD) and phenolphthalein moieties can be followed via a distinctive change of color in basic media by optical inspection. The phenolphthalein-containing lateral polymer chain was obtained via reversible addition-fragmentation chain transfer (RAFT) copolymerization of N,N-dimethylacrylamide and N-(2-hydroxy-5-(1-(4-hydroxyphenyl)-3-oxo-1,3- dihydroisobenzofuran-1-yl)benzyl)acrylamide. The RAFT polymerizations afforded statistical copolymers with molecular masses between 6900 and 8800 g mol -1 and molar mass dispersities (Crossed D sign) between 1.1 and 1.2. β-CD-functionalized building blocks were synthesized using a propargyl-functionalized chain transfer agent for the polymerization of N,N-diethylacrylamide followed by a copper(I)-catalyzed cycloaddition with β-CD-azide (Mn = 8200 g mol-1; Crossed D sign = 1.2). Self-assembly of both polymers to form supramolecular graft polymers was evidenced by 2D NOESY NMR, UV-vis spectroscopy and dynamic light scattering. © 2013 Elsevier Ltd. All rights reserved.

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ID Code: 99352
Item Type: Journal Article
Refereed: Yes
Additional Information: Cited By :9
Export Date: 5 September 2016
Correspondence Address: Barner-Kowollik, C.; Preparative Macromolecular Chemistry, Institut für Technische Chemie und Polymerchemie, Karlsruhe Institute of Technology (KIT), Engesserstraße 18, 76128 Karlsruhe, Germany; email:
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Keywords: Cyclodextrin, Reversible addition-fragmentation chain transfer (RAFT), Supramolecular graft polymer, Chain transfer agents, N ,n-diethylacrylamide, N ,n-dimethylacrylamide, RAft polymerization, Reversible addition fragmentation chain transfer (RAFT), Statistical copolymers, UV-vis spectroscopy, Visual recognition, Acrylic monomers, Cycloaddition, Cyclodextrins, Graft copolymers, Living polymerization, Supramolecular chemistry, Ultraviolet visible spectroscopy, Polymers
DOI: 10.1016/j.polymer.2013.07.031
ISSN: 00323861
Divisions: Current > Schools > School of Chemistry, Physics & Mechanical Engineering
Current > Institutes > Institute for Future Environments
Current > QUT Faculties and Divisions > Science & Engineering Faculty
Deposited On: 22 Sep 2016 04:50
Last Modified: 30 Sep 2016 01:07

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