Consecutive modular ligation as an access route to palladium containing polymers

Lang, C., Pahnke, K., Kiefer, C., Goldmann, A. S., Roesky, P. W., & Barner-Kowollik, C. (2013) Consecutive modular ligation as an access route to palladium containing polymers. Polymer Chemistry, 4(21).

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Polymers with palladium ligating moieties in the lateral chain were synthesized via consecutive CuAAC ligation. An in-depth catalyst screening was performed to optimize the reaction conditions. The obtained polymers, quantitatively loaded with palladium complexes, feature high molar masses of up to Mn = 30000 g mol-1. The complex formation is underpinned by model complex studies. 2,6-Bis(1-(p-tolyl)-1H-1,2,3-triazol-4-yl) pyridine was used as the model ligand. Reaction of the ligand with [Pd(cod)Cl2] resulted in the corresponding palladium model complex. © 2013 The Royal Society of Chemistry.

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ID Code: 99355
Item Type: Journal Article
Refereed: Yes
Additional Information: Cited By :9
Export Date: 5 September 2016
Correspondence Address: Roesky, P.W.; Institut für Anorganische Chemie, Karlsruhe Institute of Technology (KIT), Engesserstr. 15, 76131 Karlsruhe, Germany; email:
Funding Details: DFG, Deutsche Forschungsgemeinschaft
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Keywords: Catalyst screening, Complex formations, Lateral chains, Model complexes, P-tolyl, Palladium complexes, Reaction conditions, Catalysis, Chlorine compounds, Ligands, Polymers, Surgical equipment, Palladium compounds
DOI: 10.1039/c3py00648d
ISSN: 17599954
Divisions: Current > Schools > School of Chemistry, Physics & Mechanical Engineering
Current > Institutes > Institute for Future Environments
Current > QUT Faculties and Divisions > Science & Engineering Faculty
Deposited On: 22 Sep 2016 04:50
Last Modified: 29 Sep 2016 23:45

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