Spatially controlled surface immobilization of nonmodified peptides

Pauloehrl, T., Welle, A., Bruns, M., Linkert, K., Börner, H. G., Bastmeyer, M., Delaittre, G., & Barner-Kowollik, C. (2013) Spatially controlled surface immobilization of nonmodified peptides. Angewandte Chemie - International Edition, 52(37).

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A phencyclone derivative is used to achieve light-controlled immobilization of peptides possessing only natural amino acids. The photoactive precursor (blue in picture) is formed in a Diels-Alder reaction and can undergo light-triggered ring-opening reactions with amines. Successful surface patterning with a genuine c(RGDfK) peptide (green) is evidenced by imaging time-of-flight secondary-ion mass spectrometry (ToF-SIMS). Copyright © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

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ID Code: 99358
Item Type: Journal Article
Refereed: Yes
Additional Information: Cited By :12
Export Date: 5 September 2016
Correspondence Address: Barner-Kowollik, C.; Preparative Macromolecular Chemistry, Institut für Technische Chemie und Polymerchemie, Karlsruhe Institute of Technology (KIT), Engesserstraße 18, 76128 Karlsruhe, Germany; email:
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Keywords: patterning, peptides, phencyclone, photochemistry, Diels-Alder reaction, Natural amino acids, Ring opening reaction, Surface immobilization, Surface patterning, Time of flight secondary ion mass spectrometry, Amino acids, Chemical reactions, Photochemical reactions, Secondary ion mass spectrometry, immobilized protein, peptide, silane derivative, amino acid sequence, article, chemistry, cycloaddition, light, mass spectrometry, metabolism, surface property, Cycloaddition Reaction, Immobilized Proteins, Silanes, Spectrometry, Mass, Secondary Ion, Surface Properties
DOI: 10.1002/anie.201302040
ISSN: 14337851
Divisions: Current > Schools > School of Chemistry, Physics & Mechanical Engineering
Current > Institutes > Institute for Future Environments
Current > QUT Faculties and Divisions > Science & Engineering Faculty
Deposited On: 22 Sep 2016 04:50
Last Modified: 30 Sep 2016 00:33

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