Supramolecular polymer networks of building blocks prepared via RAFT polymerization

Hetzer, M., Schmidt, B. V. K. J., Barner-Kowollik, C., & Ritter, H. (2014) Supramolecular polymer networks of building blocks prepared via RAFT polymerization. Polymer Chemistry, 5(6).

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Abstract

A novel A2B3-type supramolecular polymer network was synthesized using two precision tailored building blocks: doubly-adamantyl end-capped poly(N,N-dimethylacrylamide) and a three-pronged β-cyclodextrin (β-CD) core. The polymers were prepared via reversible addition- fragmentation chain transfer (RAFT) polymerization yielding molecular weights between 4500 and 42600 g mol-1 and molar mass dispersities between 1.2 and 1.4. The β-CD trilinker was synthesized using a 1,3-cycloaddition of tripropargylamine and β-CD-azide. The supramolecular networks were prepared in aqueous media and the host-guest driven self-assembly of the building blocks was demonstrated via 2D nuclear Overhauser effect spectroscopy (NOESY) and dynamic light scattering (DLS). The rheological behavior of the polymer networks was investigated using steady shear and oscillatory shear measurements. Thereby, the influence of the molecular weight of the adamantyl-functionalized polymers, their concentration in aqueous solution and the ratio of adamantyl and β-CD groups on the viscosity were systematically evaluated. Additionally, the temperature dependence and the disruption of the host-guest interactions by addition of competitive native β-CD and potassium adamantyl carboxylate were exemplarily demonstrated. © The Royal Society of Chemistry.

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ID Code: 99387
Item Type: Journal Article
Refereed: Yes
Additional Information: Cited By :7
Export Date: 5 September 2016
Correspondence Address: Barner-Kowollik, C.; Preparative Macromolecular Chemistry, Institut für Technische Chemie und Polymerchemie, Karlsruhe Institute of Technology (KIT), Engesserstraße 18, 76128 Karlsruhe, Germany; email: christopher.barner-kowollik@kit.edu
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Keywords: Carboxylation, Cycloaddition, Dynamic light scattering, Living polymerization, Molecular weight, Supramolecular chemistry, Host guest interactions, Nuclear overhauser effect spectroscopy, Poly(N ,N-dimethylacrylamide), Reversible addition-fragmentation chain transfer, Rheological behaviors, Supramolecular networks, Supramolecular polymers, Temperature dependence, Polymers
DOI: 10.1039/c3py01624b
ISSN: 17599954
Divisions: Current > Schools > School of Chemistry, Physics & Mechanical Engineering
Current > Institutes > Institute for Future Environments
Current > QUT Faculties and Divisions > Science & Engineering Faculty
Deposited On: 22 Sep 2016 04:50
Last Modified: 27 Sep 2016 03:35

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