Adaptable hetero Diels-Alder networks for fast self-healing under mild conditions

Oehlenschlaeger, K. K., Mueller, J. O., Brandt, J., Hilf, S., Lederer, A., Wilhelm, M., Graf, R., Coote, M. L., Schmidt, F. G., & Barner-Kowollik, C. (2014) Adaptable hetero Diels-Alder networks for fast self-healing under mild conditions. Advanced Materials, 26(21).

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Abstract

A novel adaptable network based on the reversible hetero Diels-Alder reaction of a cyanodithioester and cyclopentadiene is presented. Reversible between 50-120 °C, the adjustable and self-healing features of the network are evidenced via temperature dependent rheology experiments and repetitive tensile tests whereas the network's chemical structure is explored by temperature dependent 1H MAS-NMR spectroscopy. © 2014 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

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ID Code: 99395
Item Type: Journal Article
Refereed: Yes
Additional Information: Cited By :33
Export Date: 5 September 2016
CODEN: ADVME
Funding Details: Helmholtz Association
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Keywords: Cyanodithioester, hetero Diels-Alder chemistry, Rheology, Self-healing, Nuclear magnetic resonance spectroscopy, Tensile testing, Cyclopentadienes, Diels-Alder, Hetero Diels-Alder reaction, MAS-NMR spectroscopy, Network-based, Temperature dependent, Elasticity
DOI: 10.1002/adma.201306258
ISSN: 09359648
Divisions: Current > Schools > School of Chemistry, Physics & Mechanical Engineering
Current > Institutes > Institute for Future Environments
Current > QUT Faculties and Divisions > Science & Engineering Faculty
Deposited On: 22 Sep 2016 04:50
Last Modified: 27 Sep 2016 04:39

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