Phase Inversion Membranes from Amphiphilic Diblock Terpolymers

Hörenz, C., Pietsch, C., Goldmann, A. S., Barner-Kowollik, C., & Schacher, F. H. (2015) Phase Inversion Membranes from Amphiphilic Diblock Terpolymers. Advanced Materials Interfaces, 2(8).

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Abstract

Polymeric materials as building blocks represent the most important membrane materials as they are relatively simple to synthesize and flexible regarding manufacturing conditions. In this contribution, the synthesis of amphiphilic diblock terpolymers and their use for the preparation of integral asymmetric membranes via nonsolvent induced phase separation (NIPS) processes is presented. The diblock terpolymers consist of a hydrophobic poly(styrene-co-isoprene) block and a hydrophilic segment of poly(N,N-dimethylaminoethyl methacrylate). The materials are synthesized either via nitroxide mediated polymerization or living anionic polymerization. The NIPS process is used for the fabrication of porous diblock terpolymer membranes where the membrane morphology can be influenced by several parameters such as the applied solvent mixture, open time, or relative humidity. The resulting anisotropic membranes are characterized by scanning electron microscopy and water flux measurements. Furthermore, the UV-induced crosslinking of the isoprene part of the membrane matrix is demonstrated. Stimuli responsive asymmetric membranes from amphiphilic diblock terpolymers are prepared via phase inversion processes. The diblock terpolymers are synthesized using sequential nitroxide mediated polymerization or anionic polymerization. Different membrane morphologies can be observed by varying the process parameters. pH dependent water flux performance and good stability are demonstrated for this type of ultrafiltration membranes. © 2015 Wiley-VCH Verlag GmbH & Co. KGaA.

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ID Code: 99433
Item Type: Journal Article
Refereed: Yes
Additional Information: Cited By :2
Export Date: 5 September 2016
Correspondence Address: Barner-Kowollik, C.; Preparative Macromolecular Chemistry, Institut für Technische Chemie und Polymerchemie, Karlsruhe Institute of Technology (KIT), Engesserstr. 18, Germany
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Keywords: anionic polymerization, block copolymers, membranes, nitroxide mediated polymerization, nonsolvent induced phase separation process
DOI: 10.1002/admi.201500042
ISSN: 21967350
Divisions: Current > Schools > School of Chemistry, Physics & Mechanical Engineering
Current > Institutes > Institute for Future Environments
Current > QUT Faculties and Divisions > Science & Engineering Faculty
Deposited On: 22 Sep 2016 04:50
Last Modified: 27 Sep 2016 00:04

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