Photolithographic Encoding of Metal Complexes

Lang, C., Bestgen, S., Welle, A., Müller, R., Roesky, P. W., & Barner-Kowollik, C. (2015) Photolithographic Encoding of Metal Complexes. Chemistry - A European Journal, 21(42).

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A platform technology for the creation of spatially resolved surfaces encoded with a monolayer consisting of different metal complexes was developed. The concept entails the light-triggered activation of a self- assembled monolayer (SAM) of UV-labile anchors, that is, phenacylsulfides, and the subsequent cycloaddition of selected diene-functionalized metal complexes at defined areas on the surface. The synthesis and characterization of the metal complexes for the UV-light assisted anchoring on the surface and a detailed study of a short-chain oligomer model system in solution confirm the high efficiency of the photoreaction. The hybrid materials obtained by this concept can potentially be utilized for the design of highly valuable catalytic or (opto-)electronic devices. © 2015 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

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ID Code: 99439
Item Type: Journal Article
Refereed: Yes
Additional Information: Cited By :1
Export Date: 5 September 2016
Correspondence Address: Roesky, P.W.; Institute of Inorganic Chemistry, Karlsruhe Institute of Technology (KIT), Engesserstrasse 15, Germany
Funding Details: DFG, Deutsche Forschungsgemeinschaft
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Keywords: hybrid materials, metal-complex encoding, photochemistry, photolithography, surface chemistry, Characterization, Encoding (symbols), Metal complexes, Metals, Monolayers, Photochemical reactions, Self assembled monolayers, Synthesis (chemical), Chain oligomers, Electronic device, Functionalized, High-efficiency, Photoreactions, Platform technology, Spatially resolved, Synthesis and characterizations
DOI: 10.1002/chem.201502586
ISSN: 09476539
Divisions: Current > Schools > School of Chemistry, Physics & Mechanical Engineering
Current > Institutes > Institute for Future Environments
Current > QUT Faculties and Divisions > Science & Engineering Faculty
Deposited On: 22 Sep 2016 04:50
Last Modified: 26 Sep 2016 05:36

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