Entropic Effects on the Supramolecular Self-Assembly of Macromolecules

Pahnke, K., Altintas, O., Schmidt, F. G., & Barner-Kowollik, C. (2015) Entropic Effects on the Supramolecular Self-Assembly of Macromolecules. ACS Macro Letters, 4(7).

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We report the transfer of entropic chain length effects into the realm of supramolecular chemistry and thereby demonstrate a macromolecular method to tune the reaction equilibria of hydrogen bonding motifs via the application of substituents of differing lengths and masses while not altering the actual recognition units to achieve a difference in the degree of association. The supramolecular adducts are characterized via temperature-dependent nuclear magnetic resonance (NMR) spectroscopy. (Figure Presented). © 2015 American Chemical Society.

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5 citations in Web of Science®

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ID Code: 99442
Item Type: Journal Article
Refereed: Yes
Additional Information: Cited By :3
Export Date: 5 September 2016
Correspondence Address: Barner-Kowollik, C.; Preparative Macromolecular Chemistry, Institut für Technische Chemie und Polymerchemie, Karlsruhe Institute of Technology (KIT), Engesserstr. 18, Germany
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DOI: 10.1021/acsmacrolett.5b00335
ISSN: 21611653
Divisions: Current > Schools > School of Chemistry, Physics & Mechanical Engineering
Current > Institutes > Institute for Future Environments
Current > QUT Faculties and Divisions > Science & Engineering Faculty
Deposited On: 22 Sep 2016 04:50
Last Modified: 26 Sep 2016 04:57

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