A Self-Reporting Tetrazole-Based Linker for the Biofunctionalization of Gold Nanorods

Stolzer, L., Vigovskaya, A., Barner-Kowollik, C., & Fruk, L. (2015) A Self-Reporting Tetrazole-Based Linker for the Biofunctionalization of Gold Nanorods. Chemistry - A European Journal, 21(41).

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A photochemical approach based on nitrile imine-mediated tetrazole-ene cycloaddition is introduced to functionalize gold nanorods with biomolecules. For this purpose, a bifunctional, photoreactive linker containing thioctic acid as the Au anchoring group and a tetrazole moiety for the light-induced reaction with maleimide-capped DNA was prepared. The tetrazole-based reaction on the nanoparticles' surface results in a fluorescent pyrazoline product allowing for the spectroscopic monitoring of the reaction. This first example of nitrile imine-mediated tetrazole-ene cycloaddition (NITEC)-mediated biofunctionalization of Au nanorods paves the way for the attachment of sensitive biomolecules, such as antibodies and other proteins, under mild conditions and expands the toolbox for the tailoring of nanomaterials. © 2015 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

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6 citations in Web of Science®
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ID Code: 99445
Item Type: Journal Article
Refereed: Yes
Additional Information: Cited By :4
Export Date: 5 September 2016
Correspondence Address: Barner-Kowollik, C.; Preparative Macromolecular Chemistry, Institut für Technische Chemie und Polymerchemie, Karlsruhe Institute of Technology (KIT), Engesserstrasse 18, Germany
Funding Details: GRK2039, KIT, Kumoh National Institute of Technology
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Keywords: dipolar cycloaddition, DNA, gold, nanostructures, photochemistry, Antibodies, Biomolecules, Cyanides, Cycloaddition, Nanorods, Nitrogen compounds, Photochemical reactions, Plasmons, Anchoring groups, Bi-functional, Biofunctionalization, Dipolar cycloadditions, Light induced reaction, Self-reporting, Spectroscopic monitoring, Thioctic acid
DOI: 10.1002/chem.201502070
ISSN: 09476539
Divisions: Current > Institutes > Institute for Future Environments
Current > QUT Faculties and Divisions > Science & Engineering Faculty
Deposited On: 22 Sep 2016 04:50
Last Modified: 28 Jun 2017 17:01

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