Light-driven nitrile imine-mediated tetrazole-ene cycloaddition as a versatile platform for fullerene conjugation

Sugawara, Y., Jasinski, N., Kaupp, M., Welle, A., Zydziak, N., Blasco, E., & Barner-Kowollik, C. (2015) Light-driven nitrile imine-mediated tetrazole-ene cycloaddition as a versatile platform for fullerene conjugation. Chemical Communications, 51(65).

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An efficient methodology for modular fullerene functionalization via the photo-induced nitrile imine-mediated tetrazole-ene cycloaddition (NITEC) is introduced. The versatility and platform character of the method is illustrated by the light-driven reaction of fullerenes with small molecule, polymeric and surface-immobilized tetrazoles. The efficient fullerene conjugation is evidenced via mass spectrometric techniques. © The Royal Society of Chemistry 2015.

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ID Code: 99446
Item Type: Journal Article
Refereed: Yes
Additional Information: Cited By :3
Export Date: 5 September 2016
Correspondence Address: Barner-Kowollik, C.; Preparative Macromolecular Chemistry, Institut für Technische Chemie und Polymerchemie, Karlsruhe Institute of Technology (KIT), Engesserstrasse 18, Germany; email:
Chemicals/CAS: cellulose, 61991-22-8, 68073-05-2, 9004-34-6; imine, 13774-92-0; Fullerenes; Imines; Nitriles; Tetrazoles
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Keywords: carboxyl group, cellulose, fullerene derivative, imine, nitrile, tetrazole derivative, Article, catalyst, conjugation, cycloaddition, electrospray mass spectrometry, environmental temperature, fluorescence, mass spectrometry, proton nuclear magnetic resonance, surface property, time of flight mass spectrometry, ultraviolet irradiation, chemistry, light, procedures, Cycloaddition Reaction, Fullerenes, Imines, Nitriles, Surface Properties, Tetrazoles
DOI: 10.1039/c5cc05507e
ISSN: 13597345
Divisions: Current > Schools > School of Chemistry, Physics & Mechanical Engineering
Current > Institutes > Institute for Future Environments
Current > QUT Faculties and Divisions > Science & Engineering Faculty
Deposited On: 22 Sep 2016 04:50
Last Modified: 26 Sep 2016 04:01

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