Universal mass spectrometric analysis of poly(ionic liquid)s

Cecchini, M.M., Steinkoenig, J., Reale, S., Barner, L., Yuan, J., Goldmann, A.S., De Angelis, F., & Barner-Kowollik, C. (2016) Universal mass spectrometric analysis of poly(ionic liquid)s. Chemical Science, 7(8).

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We introduce a universal high resolution mass spectrometric method for the analysis of poly(ionic liquid)s (PILs), which belong to the most challenging polyelectrolytes from an analytical perspective, by fusing high resolution collision-induced dissociation (CID)-Orbitrap mass spectrometry (MS) with supercharging agents as well as quadrupole time-of-flight (QToF) MS. The study includes a wide array of hydrophilic halide-containing PILs, which were analyzed in negative mode. The influence of the core structures (based on imidazolium, triazolium, ammonium, phosphonium and pyridinium moieties), and variable styrene-, acrylate- and vinyl-type IL polymers on the ionization behavior is mapped in detail. Variable end group functionalities were introduced via functional chain transfer agents (CTA) in reversible addition-fragmentation chain transfer (RAFT) polymerization to study their behavior during the MS analysis. Furthermore, the demanding class of vinylimidazolium halide IL polymers was investigated. The current contribution thus introduces a new analytical technology platform for an entire polymer class. © 2016 The Royal Society of Chemistry.

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4 citations in Web of Science®

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ID Code: 99456
Item Type: Journal Article
Refereed: Yes
Additional Information: Export Date: 5 September 2016
Correspondence Address: De Angelis, F.; Dipartimento di Scienze Fisiche e Chimiche, Università degli Studi dell'Aquila, Via Vetoio, Italy; email: francesco.deangelis@univaq.it
Funding Details: 639720, ERC, European Research Council
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Keywords: Chains, Free radical polymerization, Ionic liquids, Mass spectrometers, Mass spectrometry, Polyelectrolytes, Styrene, Chain transfer agents, Collision induced dissociation, End-group functionality, Mass spectrometric analysis, Orbitrap mass spectrometries, Quadrupole-time of flights, Reversible addition-fragmentation chain transfer polymerization, Spectrometric methods, Spectrometry
DOI: 10.1039/c6sc01347c
ISSN: 20416520
Divisions: Current > Schools > School of Chemistry, Physics & Mechanical Engineering
Current > Institutes > Institute for Future Environments
Current > QUT Faculties and Divisions > Science & Engineering Faculty
Deposited On: 22 Sep 2016 04:50
Last Modified: 17 May 2017 00:24

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