Universal mass spectrometric analysis of poly(ionic liquid)s

Cecchini, M. M., Steinkoenig, J., Reale, S., Barner, L., Yuan, J., Goldmann, A. S., De Angelis, F., & Barner-Kowollik, C. (2016) Universal mass spectrometric analysis of poly(ionic liquid)s. Chemical Science, 7(8).

View at publisher


We introduce a universal high resolution mass spectrometric method for the analysis of poly(ionic liquid)s (PILs), which belong to the most challenging polyelectrolytes from an analytical perspective, by fusing high resolution collision-induced dissociation (CID)-Orbitrap mass spectrometry (MS) with supercharging agents as well as quadrupole time-of-flight (QToF) MS. The study includes a wide array of hydrophilic halide-containing PILs, which were analyzed in negative mode. The influence of the core structures (based on imidazolium, triazolium, ammonium, phosphonium and pyridinium moieties), and variable styrene-, acrylate- and vinyl-type IL polymers on the ionization behavior is mapped in detail. Variable end group functionalities were introduced via functional chain transfer agents (CTA) in reversible addition-fragmentation chain transfer (RAFT) polymerization to study their behavior during the MS analysis. Furthermore, the demanding class of vinylimidazolium halide IL polymers was investigated. The current contribution thus introduces a new analytical technology platform for an entire polymer class. © 2016 The Royal Society of Chemistry.

Impact and interest:

1 citations in Scopus
Search Google Scholar™
1 citations in Web of Science®

Citation counts are sourced monthly from Scopus and Web of Science® citation databases.

These databases contain citations from different subsets of available publications and different time periods and thus the citation count from each is usually different. Some works are not in either database and no count is displayed. Scopus includes citations from articles published in 1996 onwards, and Web of Science® generally from 1980 onwards.

Citations counts from the Google Scholar™ indexing service can be viewed at the linked Google Scholar™ search.

ID Code: 99456
Item Type: Journal Article
Refereed: Yes
Additional Information: Export Date: 5 September 2016
Correspondence Address: De Angelis, F.; Dipartimento di Scienze Fisiche e Chimiche, Università degli Studi dell'Aquila, Via Vetoio, Italy; email: francesco.deangelis@univaq.it
Funding Details: 639720, ERC, European Research Council
References: Wasserscheid, P., Keim, W., (2000) Angew. Chem., Int. Ed., 39, pp. 3772-3789; Yuan, J., Antonietti, M., (2011) Polymer, 52, pp. 1469-1482; Mecerreyes, D., (2011) Prog. Polym. Sci., 36, pp. 1629-1648; Yuan, J., Mecerreyes, D., Antonietti, M., (2013) Prog. Polym. Sci., 38, pp. 1009-1036; Salamone, J.C., Israel, S.C., Taylor, P., Snider, B., (1973) Polymer, 14, pp. 639-644; Steinkoenig, J., Bloesser, F.R., Huber, B., Welle, A., Trouillet, V., Weidner, S., Barner, L., Barner-Kowollik, C., (2016) Polym. Chem., 7, pp. 451-461; Mori, H., Yahagi, M., Endo, T., (2009) Macromolecules, 42, pp. 8082-8092; Karjalainen, E., Izquierdo, D.F., Martí-Centelles, V., Luis, S.V., Tenhu, H., García-Verdugo, E., (2014) Polym. Chem., 5, pp. 1437-1446; He, H., Zhong, M., Adzima, B., Luebke, D., Nulwala, H., Matyjaszewski, K., (2013) J. Am. Chem. Soc., 135, pp. 4227-4230; He, H., Luebke, D., Nulwala, H., Matyjaszewski, K., (2014) Macromolecules, 47, pp. 6601-6609; Cordella, D., Kermagoret, A., Debuigne, A., Jérôme, C., Mecerreyes, D., Isik, M., Taton, D., Detrembleur, C., (2015) Macromolecules, 48, pp. 5230-5243; Cordella, D., Kermagoret, A., Debuigne, A., Riva, R., German, I., Isik, M., Mecerreyes, D., Detrembleur, C., (2014) ACS Macro Lett., 3, pp. 1276-1280; Marcilla, R., Blazquez, J.A., Fernandez, R., Grande, H., Pomposo, J.A., Mecerreyes, D., (2005) Macromol. Chem. Phys., 206, pp. 299-304; Prescher, S., Polzer, F., Yang, Y., Siebenbürger, M., Ballauff, M., Yuan, J., (2014) J. Am. Chem. Soc., 136, pp. 12-15; Zhang, Y., Chen, X., Lan, J., You, J., Chen, L., (2009) Chem. Biol. Drug Des., 74, pp. 282-288; Pinaud, J., Vignolle, J., Gnanou, Y., Taton, D., (2011) Macromolecules, 44, pp. 1900-1908; Hemp, S.T., Allen, M.H., Green, M.D., Long, T.E., (2012) Biomacromolecules, 13, pp. 231-238; Biswas, Y., Maji, T., Dule, M., Mandal, T.K., (2016) Polym. Chem., 7, pp. 867-877; Tang, H., Tang, J., Ding, S., Radosz, M., Shen, Y., (2005) J. Polym. Sci., Part A: Polym. Chem., 43, pp. 1432-1443; Zhang, B., Yan, X., Alcouffe, P., Charlot, A., Fleury, E., Bernard, J., (2015) ACS Macro Lett., 4, pp. 1008-1011; Grygiel, K., Lee, J.-S., Sakaushi, K., Antonietti, M., Yuan, J., (2015) ACS Macro Lett., 4, pp. 1312-1316; Coupillaud, P., Pinaud, J., Guidolin, N., Vignolle, J., Fèvre, M., Veaudecrenne, E., Mecerreyes, D., Taton, D., (2013) J. Polym. Sci., Part A: Polym. Chem., 51, pp. 4530-4540; Altuntaş, E., Schubert, U.S., (2014) Anal. Chim. Acta, 808, pp. 56-69; Gruendling, T., Weidner, S., Falkenhagen, J., Barner-Kowollik, C., (2010) Polym. Chem., 1, pp. 599-617; Banerjee, S., Mazumdar, S., (2012) Int. J. Anal. Chem., 2012, pp. 1-40; Doerr, A., (2013) Nat. Methods, 10, pp. 19-22; Gruendling, T., Hart-Smith, G., Davis, T.P., Stenzel, M.H., Barner-Kowollik, C., (2008) Macromolecules, 41, pp. 1966-1971; Gabelica, V., De Pauw, E., (2005) Mass Spectrom. Rev., 24, pp. 566-587; Sleno, L., Volmer, D.A., (2004) J. Mass Spectrom., 39, pp. 1091-1112; Dobrynin, A.V., Rubinstein, M., (2005) Prog. Polym. Sci., 30, pp. 1049-1118; Teo, C.A., Donald, W.A., (2014) Anal. Chem., 86, pp. 4455-4462; Douglass, K.A., Venter, A.R., (2012) J. Am. Soc. Mass Spectrom., 23, pp. 489-497; Iavarone, A.T., Williams, E.R., (2003) J. Am. Chem. Soc., 125, pp. 2319-2327; Erdmenger, T., Vitz, J., Wiesbrock, F., Schubert, U.S., (2008) J. Mater. Chem., 18, pp. 5267-5273; Maton, C., De Vos, N., Stevens, C.V., (2013) Chem. Soc. Rev., 42, pp. 5963-5977; Ohtani, H., Ishimura, S., Kumai, M., (2008) Anal. Sci., 24, pp. 1335-1340; Crosthwaite, J.M., Muldoon, M.J., Dixon, J.K., Anderson, J.L., Brennecke, J.F., (2005) J. Chem. Thermodyn., 37, pp. 559-568; Kohno, Y., Saita, S., Men, Y., Yuan, J., Ohno, H., (2015) Polym. Chem., 6, pp. 2163-2178; Hemp, S.T., Zhang, M., Allen, M.H., Cheng, S., Moore, R.B., Long, T.E., (2013) Macromol. Chem. Phys., 214, pp. 2099-2107; Borguet, Y.P., Tsarevsky, N.V., (2012) Polym. Chem., 3, pp. 2487-2494; Xue, Y., Xiao, H., Zhang, Y., (2015) Int. J. Mol. Sci., 16, pp. 3626-3655; Ye, Y., Elabd, Y.A., (2011) Macromolecules, 44, pp. 8494-8503; Baines, F.C., Bevington, J.C., (1968) J. Polym. Sci., Part A-1, 6, pp. 2433-2440; Gody, G., Maschmeyer, T., Zetterlund, P.B., Perrier, S., (2013) Nat. Commun., 4, pp. 2505-2514; Binder, W.H., Sachsenhofer, R., (2008) Macromol. Rapid Commun., 29, pp. 952-981; Barner-Kowollik, C., Du Prez, F.E., Espeel, P., Hawker, C.J., Junkers, T., Schlaad, H., Van Camp, W., (2011) Angew. Chem., Int. Ed., 50, pp. 60-62; Kaupp, M., Tischer, T., Hirschbiel, A.F., Vogt, A.P., Geckle, U., Trouillet, V., Hofe, T., Barner-Kowollik, C., (2013) Macromolecules, 46, pp. 6858-6872; Oehlenschlaeger, K.K., Mueller, J.O., Heine, N.B., Glassner, M., Guimard, N.K., Delaittre, G., Schmidt, F.G., Barner-Kowollik, C., (2013) Angew. Chem., Int. Ed., 52, pp. 762-766; Obadia, M.M., Drockenmuller, E., (2016) Chem. Commun., 52, pp. 2433-2450; Fodor, C., Bozi, J., Blazsó, M., Iván, B., (2012) Macromolecules, 45, pp. 8953-8960; Bingöl, B., Hart-Smith, G., Barner-Kowollik, C., Wegner, G., (2008) Macromolecules, 41, pp. 1634-1639; Junkers, T., Barner-Kowollik, C., (2008) J. Polym. Sci., Part A: Polym. Chem., 46, pp. 7585-7605; Hunt, S.M., Sheil, M.M., Belov, M., Derrick, P.J., (1998) Anal. Chem., 70, pp. 1812-1822; Thomson, B.A., (1997) J. Am. Soc. Mass Spectrom., 8, pp. 1053-1058
Keywords: Chains, Free radical polymerization, Ionic liquids, Mass spectrometers, Mass spectrometry, Polyelectrolytes, Styrene, Chain transfer agents, Collision induced dissociation, End-group functionality, Mass spectrometric analysis, Orbitrap mass spectrometries, Quadrupole-time of flights, Reversible addition-fragmentation chain transfer polymerization, Spectrometric methods, Spectrometry
DOI: 10.1039/c6sc01347c
ISSN: 20416520
Divisions: Current > Schools > School of Chemistry, Physics & Mechanical Engineering
Current > Institutes > Institute for Future Environments
Current > QUT Faculties and Divisions > Science & Engineering Faculty
Deposited On: 22 Sep 2016 04:50
Last Modified: 23 Sep 2016 00:32

Export: EndNote | Dublin Core | BibTeX

Repository Staff Only: item control page