Chain Transfer in Degenerative RAFT Polymerization Revisited: A Comparative Study of Literature Methods

Derboven, P., Van Steenberge, P. H. M., Reyniers, M. F., Barner-Kowollik, C., D'Hooge, D. R., & Marin, G. B. (2016) Chain Transfer in Degenerative RAFT Polymerization Revisited: A Comparative Study of Literature Methods. Macromolecular Theory and Simulations, 25(2).

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Abstract

Under the validity of the degenerative transfer mechanism, the activation/deactivation process in reversible addition-fragmentation chain transfer (RAFT) polymerization can be formally quantified by transfer coefficients, depending on the chemical structure of the participating radicals and dormant species. In the present work, the different literature methods to experimentally determine these RAFT transfer coefficients are reviewed and theoretically re-evaluated. The accuracy of each method is mapped for a broad range of reaction conditions and RAFT transfer reactivities. General guidelines on when which method should be applied are formulated. (Figure presented.) . © 2016 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim

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ID Code: 99458
Item Type: Journal Article
Refereed: Yes
Additional Information: Export Date: 5 September 2016
CODEN: MTHSE
Correspondence Address: Barner-Kowollik, C.; Preparative Macromolecular Chemistry, Institut für Technische Chemie und Polymerchemie, Karlsruhe Institute of Technology (KIT), Engesserstrasse 18, Germany; email: christopher.barner-kowollik@kit.edu
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Keywords: kinetics (polym.), modeling, radical polymerization, reversible addition fragmentation chain transfer (RAFT), Chains, Living polymerization, Models, Polymerization, Activation/deactivation, Degenerative transfer, Kinetics(polym.), RAft polymerization, Reaction conditions, Reversible addition fragmentation chain transfer, Reversible addition-fragmentation chain transfer polymerization, Transfer coefficient, Free radical polymerization
DOI: 10.1002/mats.201500076
ISSN: 10221344
Divisions: Current > Schools > School of Chemistry, Physics & Mechanical Engineering
Current > Institutes > Institute for Future Environments
Current > QUT Faculties and Divisions > Science & Engineering Faculty
Deposited On: 22 Sep 2016 04:50
Last Modified: 23 Sep 2016 01:01

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