Bis(mesitoyl)phosphinic acid: Photo-triggered release of metaphosphorous acid in solution

Fast, D. E., Zalibera, M., Lauer, A., Eibel, A., Schweigert, C., Kelterer, A. M., Spichty, M., Neshchadin, D., Voll, D., Ernst, H., Liang, Y., Dietliker, K., Unterreiner, A. N., Barner-Kowollik, C., Grützmacher, H., & Gescheidt, G. (2016) Bis(mesitoyl)phosphinic acid: Photo-triggered release of metaphosphorous acid in solution. Chemical Communications, 52(64).

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Abstract

Bis(mesitoyl)phosphinic acid and its sodium salt display a unique photo-induced reactivity: both derivatives stepwise release two mesitoyl radicals and, remarkably, metaphosphorous acid (previously postulated as transient species in the gas phase), providing a new phosphorus-based reagent. © 2016 The Royal Society of Chemistry.

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ID Code: 99459
Item Type: Journal Article
Refereed: Yes
Additional Information: Export Date: 5 September 2016
CODEN: CHCOF
Correspondence Address: Gescheidt, G.; Institute of Physical and Theoretical Chemistry, NAWI Graz, Graz University of Technology, Stremayrgasse 9, Austria; email: g.gescheidt-demner@tugraz.at
Chemicals/CAS: phosphorous acid, 13598-36-2; phosphorus, 7723-14-0; sodium, 7440-23-5
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Keywords: bis(mesitoyl)phosphinic acid, metaphosphorous acid, phosphinic acid derivative, phosphorous acid, phosphorus, sodium, unclassified drug, Article, photolysis, polymerization
DOI: 10.1039/c6cc05219c
ISSN: 13597345
Divisions: Current > Schools > School of Chemistry, Physics & Mechanical Engineering
Current > Institutes > Institute for Future Environments
Current > QUT Faculties and Divisions > Science & Engineering Faculty
Deposited On: 22 Sep 2016 04:50
Last Modified: 23 Sep 2016 01:18

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