A mild, efficient and catalyst-free thermoreversible ligation system based on dithiooxalates

Pahnke, K., Haworth, N. L., Brandt, J., Paulmann, U., Richter, C., Schmidt, F. G., Lederer, A., Coote, M. L., & Barner-Kowollik, C. (2016) A mild, efficient and catalyst-free thermoreversible ligation system based on dithiooxalates. Polymer Chemistry, 7(19).

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Abstract

We demonstrate a novel and ready to prepare thermoreversible hetero Diels-Alder dilinker on the basis of dithiooxalates, enabling the mild, rapid and catalyst-free linkage of diverse diene species under ambient conditions for applications in the fields of, for example, modular ligation, self-healing or recyclable materials and surface modification amongst others. The linker was studied using quantum chemical calculations, and experimentally in small molecular reactions via UV/Vis spectroscopy, mass spectrometry and NMR as well as in step-growth polymerizations with diene-difunctional building blocks-characterized via (temperature dependent) SEC and HT NMR-as an example for efficient polymer ligation. © The Royal Society of Chemistry 2016.

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ID Code: 99475
Item Type: Journal Article
Refereed: Yes
Additional Information: Export Date: 5 September 2016
Correspondence Address: Lederer, A.; Leibniz-Institut für Polymerforschung Dresden, Hohe Str. 6, Germany; email: lederer@ipfdd.de
Funding Details: DFG, Kumoh National Institute of Technology
Funding Details: KIT, Kumoh National Institute of Technology
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DOI: 10.1039/c6py00470a
ISSN: 17599954
Divisions: Current > Schools > School of Chemistry, Physics & Mechanical Engineering
Current > Institutes > Institute for Future Environments
Current > QUT Faculties and Divisions > Science & Engineering Faculty
Deposited On: 22 Sep 2016 04:50
Last Modified: 25 Sep 2016 23:22

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