Maleimide-functionalized poly(2-ethyl-2-oxazoline): Synthesis and reactivity

Wendler, F., Rudolph, T., Görls, H., Jasinski, N., Trouillet, V., Barner-Kowollik, C., & Schacher, F. H. (2016) Maleimide-functionalized poly(2-ethyl-2-oxazoline): Synthesis and reactivity. Polymer Chemistry, 7(13).

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Poly(2-ethyl-2-oxazoline)s (PEtOx23 - Mn = 2300 g mol-1, D = 1.07; PEtOx46 - Mn = 4400 g mol-1, D = 1.06) end-functionalized with a maleimide moiety were prepared from azide-terminated PEtOxx-N3via copper-catalyzed azide-alkyne cycloaddition (CuAAC) with an alkyne-bearing maleimide (MI). The latter has been synthesized in a three-step procedure, including protection of the maleimide double bond prior to the modification of PEtOx. PEtOxx-MI was characterized by NMR (1H, 13C), SEC, FT-IR, and MALDI-ToF MS and, after deprotection of the maleimide, used in nitrile imine-mediated tetrazole-ene cycloaddition (NITEC) processes for covalent attachment to silicon surfaces in a grafting-to approach. © The Royal Society of Chemistry 2016.

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ID Code: 99480
Item Type: Journal Article
Refereed: Yes
Additional Information: Export Date: 5 September 2016
Correspondence Address: Schacher, F.H.; Institute of Organic and Macromolecular Chemistry (IOMC), Friedrich Schiller University Jena, Humboldtstr. 10, Germany; email:
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Keywords: Chemistry, Azide-alkyne cycloaddition, Copper catalyzed, Covalent attachment, Functionalized, MALDI TOF MS, Poly(2-ethyl-2-oxazoline), Poly(2ethyl-2-oxazoline)s, Silicon surfaces, Hydrocarbons
DOI: 10.1039/c6py00033a
ISSN: 17599954
Divisions: Current > Schools > School of Chemistry, Physics & Mechanical Engineering
Current > Institutes > Institute for Future Environments
Current > QUT Faculties and Divisions > Science & Engineering Faculty
Deposited On: 22 Sep 2016 04:50
Last Modified: 25 Sep 2016 21:48

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