Modified porphyrinoids from carbazates and hydrazones and the first crystal structure of a di-iminoporphodimethene

Esdaile, Louisa J. and McMurtrie, John C. and Turner, Peter. and Arnold, Dennis P. (2005) Modified porphyrinoids from carbazates and hydrazones and the first crystal structure of a di-iminoporphodimethene. Tetrahedron Letters 46(40):pp. 6931-6935.

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Abstract

Novel porphyrinoids with interrupted conjugation (di-iminoporphodimethenes) result from the Pd-catalyzed coupling of meso-bromo porphyrins and their metal complexes with carbazates and hydrazones, followed by aerial oxidation. X-Ray crystallography revealed a saddle shape for molecules of the nickel(II) complex of a di-iminoporphodimethene.

Item Type:	Journal Article
RM Number:	2006001857
Status:	Published
Keywords:	porphyrins; carbazate; porphodimethene; crystal structure
Subjects:	250000 Chemical Sciences > 250300 Organic Chemistry
ID Code:	1937
Deposited By:	Arnold, Dennis
Deposited On:	04 August 2005
Alternative Locations:	http://dx.doi.org/10.1016/j.tetlet.2005.08.004
Copyright Owner:	Copyright 2005 Elsevier
Copyright Statement:	Reproduced in accordance with the copyright policy of the publisher.