XPS study of basic aluminium sulphate and basic aluminium nitrate

Duong, Loc V., Wood, Barry J., & Kloprogge, J. Theo (2005) XPS study of basic aluminium sulphate and basic aluminium nitrate. Materials Letters, 59(14/15), pp. 1932-1936.

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Basic aluminium sulphate and nitrate crystals were prepared by forced hydrolysis of aluminium salt solution followed by precipitation with a sulphate solution or by evaporation for the basic aluminium nitrate. X-ray Photoelectron Spectroscopy (XPS) confirms the chemical composition determined by ICP-AES in earlier work. High resolution XPS scans of the individual elements allow the identification of both the central IVAlO4 group and the 12 aluminium octahedra in the [IVAlO4AlVI(OH)24(H2O)12] building unit by two Al 2p transitions with binding energies of 73.7 and 74.2 eV in both the basic aluminium sulphate and nitrate. Four different types of oxygen atoms were identified in the basic aluminium sulphate associated with the central AlO4, OH, H2O and SO4 groups in the crystal structure with transitions at 529.4, 530.1, 530.7 and 531.8 eV, respectively.

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23 citations in Web of Science®
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ID Code: 1275
Item Type: Journal Article
Refereed: Yes
Keywords: Al13, Basic aluminium nitrate, Basic aluminium sulphate, Characterisation methods, Keggin structure, X, ray techniques
DOI: 10.1016/j.matlet.2005.02.029
ISSN: 0167-577X
Subjects: Australian and New Zealand Standard Research Classification > CHEMICAL SCIENCE (030000) > INORGANIC CHEMISTRY (030200)
Divisions: Past > QUT Faculties & Divisions > Faculty of Science and Technology
Copyright Owner: Copyright 2005 Elsevier
Copyright Statement: Reproduced in accordance with the copyright policy of the publisher.
Deposited On: 19 Jul 2006 00:00
Last Modified: 10 Aug 2011 18:24

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