Porphyrin-Containing Rotaxane Assemblies
Description
Porphyrins have been widely recognized for their unique photo‐ and electrochemical properties as well as their crucial roles in a wide variety of biological processes including catalysis, oxygen transport, and photosynthesis. In addition, their size and predictable coordination geometries makes them attractive components in the assembly of functional supramolecular assemblies. Advances in porphyrin synthesis have enabled their incorporation into rotaxanes not only as stoppers but also as components of the macrocycle, or even higher order rotaxane architectures, each design imparting unique functionality either through redox, fluorescence, or coordination environment. Here we describe advances in the synthesis of increasingly complex porphyrin‐containing rotaxane assemblies and their dynamic properties that arise from the porphyrin inclusion.
Impact and interest:
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| ID Code: | 129798 | ||
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| Item Type: | Contribution to Journal (Review article) | ||
| Refereed: | Yes | ||
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| Measurements or Duration: | 13 pages | ||
| Keywords: | Interlocked molecules, Porphyrins, Rotaxanes, Supramolecular chemistry, Template synthesis | ||
| DOI: | 10.1002/ejoc.201900202 | ||
| ISSN: | 1434-193X | ||
| Pure ID: | 33468084 | ||
| Divisions: | Past > Institutes > Institute for Future Environments Past > QUT Faculties & Divisions > Science & Engineering Faculty |
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| Funding Information: | Figure 7. Gunter et al. example of utilizing metalloporphyrin-ligand coordination in the thermodynamic self-assembly of [2]rotaxane 7. Reproduced from ref.[30c] with permission from the Centre National de la Recherche Scientifique (CNRS) and The Royal Society of Chemistry. The work referenced in this review was supported by the Australian Research Council, DP110100631 and Queensland University of Technology support from the Central Analytical Research Facility operated by the Institute for Future Environments. Kathleen Mullen gained her PhD from the University of New England, Australia, under the supervision of Professor Max Gunter. Following postdoctoral fellowships with Professor Paul Beer at the University of Oxford and Professor David Leigh at University of Edinburgh, Dr Mullen was awarded an ARC Australian Postdoctoral Fellowship and lectureship at Queensland University of Technology. Her work has focused primarily on the construction of interpenetrated and interlocked systems both in solution and on solid surfaces. | ||
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| Copyright Owner: | Consult author(s) regarding copyright matters | ||
| Copyright Statement: | This work is covered by copyright. Unless the document is being made available under a Creative Commons Licence, you must assume that re-use is limited to personal use and that permission from the copyright owner must be obtained for all other uses. If the document is available under a Creative Commons License (or other specified license) then refer to the Licence for details of permitted re-use. It is a condition of access that users recognise and abide by the legal requirements associated with these rights. If you believe that this work infringes copyright please provide details by email to qut.copyright@qut.edu.au | ||
| Deposited On: | 28 May 2019 23:11 | ||
| Last Modified: | 11 Jul 2024 13:16 |
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