Arrangement models of alkylammonium cations in the interlayer of HDTMA+ pillared montmorillonites
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Description
The orientation of HDTMA+ in the interlayer of organic pillared montmorillonites prepared at different concentrations of HDTMA+ have been studied using X-ray powder diffraction (XRD) and theoretical calculation. A series of arrangement models of HDTMA+ in the interlayer of montmorillonite have been proposed as lateral-monolayer (LM), lateral-bilayer (LB), pseudotrilayer (PT), paraffin-type-monolayer (PM), paraffin-type-bilayer (PB). With the increase of the concentration of HDTMA+, the arrangement model of HDTMA+ in the interlayer of montmorillonites changes as lateral-monolayer→lateral-bilayer→paraffin-type monolayer→pseudotrilayer→paraffin-type-bilayer and the packing density of HDTMA+ in the interlayer increases gradually. In the intermediate stages, different models may coexist.
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ID Code: | 1517 |
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Item Type: | Contribution to Journal (Journal Article) |
Refereed: | Yes |
Additional Information: | h.he@qut.edu.au |
Keywords: | organic pillared montmorillonite, arrangement model, XRD, HDTMA+, nanochemistry, organoclay, clay, based nanocomposites |
ISSN: | 1001-6538 |
Pure ID: | 60068794 |
Divisions: | Past > QUT Faculties & Divisions > Faculty of Science and Technology Past > Research Centres > CRC for Diagnostics |
Copyright Owner: | Copyright 2003 World Scientific |
Copyright Statement: | Electronic version of an article published as Chinese Science Bulletin 48(4):pp. 368-372. |
Deposited On: | 11 Jul 2006 00:00 |
Last Modified: | 29 Jul 2024 08:15 |
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