Profluorescent nitroxide sensors for monitoring the natural aging of polymer materials
Description
The utility of profluorescent nitroxides (PFNs) as sensitive probes to detect early stage photodegradation in a cyclic olefin copolymer, TOPAS®, during both natural aging and accelerated aging under laboratory conditions is reported. PFN additives in TOPAS® capture radicals to form fluorescent adducts as the material degrades. The levels of fluorescence detectable from the polymer reflect the degree of free-radical degradation in the material, with the PFN probes delivering enhanced sensitivity over traditional analytical methods for the detection of photodegradation of TOPAS®. The probes are able to highlight polymer degradation occurring within the oxidation “induction” period, where little change can be observed using infrared spectroscopy; however, their efficacy does not extend far beyond this period. The effective probe lifetime however can be significantly extended through the use of common additives such as the UV absorber (Tinuvin P) and a hindered amine stabiliser analogue (1,1,3,3-tetramethylisoindol-2-yloxyl, TMIO).
Impact and interest:
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ID Code: | 197747 | ||||||||
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Item Type: | Contribution to Journal (Journal Article) | ||||||||
Refereed: | Yes | ||||||||
ORCID iD: |
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Measurements or Duration: | 11 pages | ||||||||
Keywords: | Perylenediimide, Photodegradation, Profluorescent nitroxide, Sensor, TOPAS, Weathering | ||||||||
DOI: | 10.1016/j.polymdegradstab.2020.109091 | ||||||||
ISSN: | 0141-3910 | ||||||||
Pure ID: | 45669220 | ||||||||
Divisions: | Current > Research Centres > Centre for Materials Science Past > Institutes > Institute for Future Environments Past > QUT Faculties & Divisions > Science & Engineering Faculty Current > QUT Faculties and Divisions > Faculty of Science Current > Schools > School of Chemistry & Physics Current > Research Centres > Centre for Tropical Crops and Biocommodities |
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Copyright Owner: | Elsevier Ltd | ||||||||
Copyright Statement: | This work is covered by copyright. Unless the document is being made available under a Creative Commons Licence, you must assume that re-use is limited to personal use and that permission from the copyright owner must be obtained for all other uses. If the document is available under a Creative Commons License (or other specified license) then refer to the Licence for details of permitted re-use. It is a condition of access that users recognise and abide by the legal requirements associated with these rights. If you believe that this work infringes copyright please provide details by email to qut.copyright@qut.edu.au | ||||||||
Deposited On: | 19 Mar 2020 00:32 | ||||||||
Last Modified: | 17 Apr 2024 21:45 |
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