Exploring Aluminum-Ion Insertion into Magnesium-Doped Manjiroite (MnO2) Nanorods in Aqueous Solution
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Description
Aqueous aluminum-ion batteries are promising for sustainable energy storage given the abundance of aluminum and the ease of recycling. However, finding suitable electrode materials that can intercalate Al ions remains challenging. Here, we investigate Mg-ion-doped MnO2 nanorods in the manjiroite structure that allow Al-ion insertion into the open tunnels of this material. The electrode material is characterized before and after Al-ion insertion with X-ray diffraction and X-ray photoelectron spectroscopy, and the insertion process is studied via in situ transmission electron microscopy, which highlights a change in the length of the MnO2 nanorod. The results indicate that Al ions can be successfully inserted into the MnO2 nanorods, which has also been determined by density functional theory calculations to be an energetically favorable process. The electrochemical data indicate that diffusion-controlled Al insertion as well as a surface pseudocapacitive effect occur. This indicates that MnO2 nanomaterials synthesized in the presence of metal cations is potentially a viable route for facilitating their use as electrode materials in aqueous Al-ion batteries or supercapatteries.
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ID Code: | 207351 | ||||||||||||||||
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Item Type: | Contribution to Journal (Journal Article) | ||||||||||||||||
Refereed: | Yes | ||||||||||||||||
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Additional Information: | Funding Information: The XPS, XRD and SEM data reported in this paper were obtained at the Central Analytical Research Facility operated by the Institute for Future Environments (QUT). Access to CARF is supported by generous funding from the Science and Engineering Faculty. A.O.M. and K.O. acknowledge partial support from the Australian Research Council. J.F.S.F. and D.G. are grateful to the Australian Research Council (ARC) for funding in the frame of a Laureate Fellowship FL160100089. | ||||||||||||||||
Measurements or Duration: | 7 pages | ||||||||||||||||
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Keywords: | aluminum-ion batteries, energy storage, in situ transmission electron microscopy, MnO nanorods, multivalent batteries | ||||||||||||||||
DOI: | 10.1002/celc.202001408 | ||||||||||||||||
ISSN: | 2196-0216 | ||||||||||||||||
Pure ID: | 74445049 | ||||||||||||||||
Divisions: | Current > Research Centres > Centre for Materials Science Current > Research Centres > Centre for Clean Energy Technologies & Practices Current > QUT Faculties and Divisions > Faculty of Science Current > Schools > School of Chemistry & Physics |
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Funding Information: | The XPS, XRD and SEM data reported in this paper were obtained at the Central Analytical Research Facility operated by the Institute for Future Environments (QUT). Access to CARF is supported by generous funding from the Science and Engineering Faculty. A.O.M. and K.O. acknowledge partial support from the Australian Research Council. J.F.S.F. and D.G. are grateful to the Australian Research Council (ARC) for funding in the frame of a Laureate Fellowship FL160100089. | ||||||||||||||||
Copyright Owner: | 2020 Wiley-VCH GmbH | ||||||||||||||||
Copyright Statement: | This work is covered by copyright. Unless the document is being made available under a Creative Commons Licence, you must assume that re-use is limited to personal use and that permission from the copyright owner must be obtained for all other uses. If the document is available under a Creative Commons License (or other specified license) then refer to the Licence for details of permitted re-use. It is a condition of access that users recognise and abide by the legal requirements associated with these rights. If you believe that this work infringes copyright please provide details by email to qut.copyright@qut.edu.au | ||||||||||||||||
Deposited On: | 15 Jan 2021 03:49 | ||||||||||||||||
Last Modified: | 01 Jul 2024 03:28 |
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