Promoting nickel catalysts by visible-light illuminated gold and palladium nanoparticles
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Xiayan Wu Thesis
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Available under License Creative Commons Attribution Non-commercial No Derivatives 4.0. |
Description
This research focuses on promoting nickel-based catalysts by visible-light illuminated gold and palladium nanoparticles in fine organic synthesis. Using lignin model compound cleavage as the model reaction, the performance of three distinct systems, in-situ formed Ni(OH)2 on ZrO2 supported Au NPs, non-plasmonic NiPd alloy NPs supported on ZrO2 and the mechanical mixture of ZrO2 supported Au NPs and Ni NPs are investigated. Ultra-low palladium loading on sodium titanate sheets for Heck cross-coupling reaction under visible light is also studied. This research has provided innovative findings in new photocatalyst design and application.
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ID Code: | 227208 |
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Item Type: | QUT Thesis (PhD) |
Supervisor: | Zhu, Huai Yong & Waclawik, Eric |
Keywords: | Photocatalysis, Plasmonic photocatalysts, Visible light, Lignin model compounds, Surface plasmon resonance, Organic synthesis, Cross-coupling reactions |
DOI: | 10.5204/thesis.eprints.227208 |
Divisions: | Current > QUT Faculties and Divisions > Faculty of Science Current > Schools > School of Chemistry & Physics |
Institution: | Queensland University of Technology |
Deposited On: | 18 Jan 2022 02:55 |
Last Modified: | 18 Jan 2022 05:04 |
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