Promoting nickel catalysts by visible-light illuminated gold and palladium nanoparticles

Wu, Xiayan (2021) Promoting nickel catalysts by visible-light illuminated gold and palladium nanoparticles. PhD thesis, Queensland University of Technology.

Description

This research focuses on promoting nickel-based catalysts by visible-light illuminated gold and palladium nanoparticles in fine organic synthesis. Using lignin model compound cleavage as the model reaction, the performance of three distinct systems, in-situ formed Ni(OH)2 on ZrO2 supported Au NPs, non-plasmonic NiPd alloy NPs supported on ZrO2 and the mechanical mixture of ZrO2 supported Au NPs and Ni NPs are investigated. Ultra-low palladium loading on sodium titanate sheets for Heck cross-coupling reaction under visible light is also studied. This research has provided innovative findings in new photocatalyst design and application.

Impact and interest:

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89 since deposited on 18 Jan 2022
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ID Code: 227208
Item Type: QUT Thesis (PhD)
Supervisor: Zhu, Huai Yong & Waclawik, Eric
Keywords: Photocatalysis, Plasmonic photocatalysts, Visible light, Lignin model compounds, Surface plasmon resonance, Organic synthesis, Cross-coupling reactions
DOI: 10.5204/thesis.eprints.227208
Divisions: Current > QUT Faculties and Divisions > Faculty of Science
Current > Schools > School of Chemistry & Physics
Institution: Queensland University of Technology
Deposited On: 18 Jan 2022 02:55
Last Modified: 18 Jan 2022 05:04