Understanding of lambda-orthogonal photo-induced reaction systems
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Philipp Willi Kamm Thesis
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Available under License Creative Commons Attribution Non-commercial No Derivatives 4.0. |
Description
Using light as an energy source allows chemical reactions to be carried out with high precision in time and space. In time, because light can be switched on and off, in space, because light can be highly focussed. Further, different colours of light can be used to activate different reactants individually, even when they are present in the same reaction mixture. Herein, a system of two light-sensitive molecules was developed, which react completely sequence-independently with UV or visible light. The wavelength-dependence as well as the influence of chemical-physical parameters on such reactions were investigated in-depth.
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| ID Code: | 234293 |
|---|---|
| Item Type: | QUT Thesis (PhD) |
| Supervisor: | Barner-Kowollik, Christopher & Blinco, James |
| Keywords: | lambda-orthogonality, photochemistry, wavelength-dependence, nitrile imine, 1,3-dipolar cycloaddition, tetrazole, action plot, o-methylbenzaldehyde, styrylpyrene, quantum yield |
| DOI: | 10.5204/thesis.eprints.234293 |
| Divisions: | Current > QUT Faculties and Divisions > Faculty of Science Current > Schools > School of Chemistry & Physics |
| Institution: | Queensland University of Technology |
| Deposited On: | 02 Sep 2022 03:37 |
| Last Modified: | 02 Sep 2022 03:37 |
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