Modulation and tuning of spin crossover by encapsulation of metal complexes within halogen-bonded architectures
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Andres Reyes Zuluaga Thesis.pdf. Available under License Creative Commons Attribution Non-commercial No Derivatives 4.0. |
Description
This project aimed to establish a way to modulate the supramolecular chemistry and spin crossover properties of metal complexes through the use of anionic supramolecular networks. This research employed crystal engineering to effectively combine several molecular building blocks within the same crystalline material. The arrangement of these components within these crystalline materials and their associated magnetic properties were regulated through the use of a variety of different molecular components, resulting in the development of a variety of novel co-crystals, with potential applications as molecular sensors, switches and data storage or memory devices.
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| ID Code: | 235893 |
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| Item Type: | QUT Thesis (PhD) |
| Supervisor: | Micallef, Aaron, McMurtrie, John, & Mullen, Kathleen |
| Keywords: | crystal engineering, halogen bonding, metal complex, X-ray diffraction, solvent exchange, spin crossover, spin transition, supramolecular chemistry, crystallography, single crystal |
| DOI: | 10.5204/thesis.eprints.235893 |
| Pure ID: | 116485867 |
| Divisions: | Current > QUT Faculties and Divisions > Faculty of Science Current > Schools > School of Chemistry & Physics |
| Institution: | Queensland University of Technology |
| Deposited On: | 28 Oct 2022 06:28 |
| Last Modified: | 25 Jan 2023 02:08 |
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