Probing topology, selectivity and reactivity of complex metallosupramolecular assemblies
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Description
There are limited examples of low-symmetry or high complexity metallo-supramolecular systems which is attributed to the difficulties in structure characterisation using traditional methods of analysis. This is a problem because there are numerous potential applications for such systems in catalysis, molecular sensing and switching and more. This project set out to examine such systems using a new technique known as the cyclic Ion Mobility Mass Spectrometry (cIM-MS). This research found that using cIM-MS provided a deeper understanding of the chemical and structural complexity of these metallo-supramolecular systems which was not possible before.
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| ID Code: | 242131 |
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| Item Type: | QUT Thesis (Master of Philosophy) |
| Supervisor: | Mullen, Kathleen & McMurtrie, John |
| Keywords: | Metallo-supramolecular Assemblies, Ion Mobility Mass Spectrometry, High Complexity Systems, Cages, Self-Assembly, cIM-MS, Metallo-supramolecular Mixtures |
| DOI: | 10.5204/thesis.eprints.242131 |
| Pure ID: | 141294079 |
| Divisions: | Current > QUT Faculties and Divisions > Faculty of Science Current > Schools > School of Chemistry & Physics |
| Institution: | Queensland University of Technology |
| Deposited On: | 04 Aug 2023 05:31 |
| Last Modified: | 04 Aug 2023 05:31 |
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