Characterization of Intercalated Ni/Al Hydrotalcites Prepared By The Partial Decomposition of Urea

, , Trujillano, Raquel, Holgado, Maria, San Roman, M, Rives, V, , & (2006) Characterization of Intercalated Ni/Al Hydrotalcites Prepared By The Partial Decomposition of Urea. Crystal Growth and Design, 6(6), pp. 1533-1536.

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Description

Layered double hydroxides containing Ni2+ and Al3+ have been synthetized by homogeneous precipitation through urea hydrolysis. The nature of the interlayer species changes according to the treatment of the samples, formation of interlayer (NH2)COO- species being observed immediately after precipitation, which undergo transformation to carbonate after hydrothermal treatment. Simultaneously, liberation of ammonia during decomposition under hydrothermal conditions gives rise to formation of [Ni(NH3)6]2+ species in solution.

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ID Code: 4566
Item Type: Contribution to Journal (Journal Article)
Refereed: Yes
ORCID iD:
Martens, Waydeorcid.org/0000-0002-0959-6838
Measurements or Duration: 4 pages
Keywords: Hydrotalcite, Mid-Infrared Spectroscopy, Raman Spectroscopy, Urea Decomposition
DOI: 10.1021/cg0504612
ISSN: 1528-7483
Pure ID: 33887528
Divisions: Past > QUT Faculties & Divisions > Faculty of Science and Technology
Past > QUT Faculties & Divisions > Science & Engineering Faculty
Current > Research Centres > Australian Research Centre for Aerospace Automation
Copyright Owner: Consult author(s) regarding copyright matters
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Deposited On: 22 Jun 2006 00:00
Last Modified: 29 Jul 2024 17:31