Controlled Adsorption Orientation for Double-Decker Complexes
Description
Control of the molecular orientation of double-decker complexes comprised of rare-earth metals sandwiched with naphthalocyanine and porphyrin/phthalocyanine, at the interface of a graphite surface and 1-phenyloctane solution, has been demonstrated for the future application of molecular rotor assembly. Scanning tunneling microscope images clarified the internal structures of the top ligands. The observed images indicate that naphthalocyanine ligands were selectively adsorbed onto the graphite surface and the counterpart ligands of porphyrin/phthalocyanine were oriented off the surface. Control of the orientation of monolayers of mixed double-decker complexes has also been demonstrated.
Impact and interest:
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| ID Code: | 6376 |
|---|---|
| Item Type: | Contribution to Journal (Journal Article) |
| Refereed: | Yes |
| Measurements or Duration: | 4 pages |
| DOI: | 10.1021/jp063309z |
| ISSN: | 1932-7447 |
| Pure ID: | 33741105 |
| Divisions: | Past > QUT Faculties & Divisions > Faculty of Science and Technology Past > Schools > School of Physical & Chemical Sciences Past > QUT Faculties & Divisions > Science & Engineering Faculty Current > Research Centres > Australian Research Centre for Aerospace Automation |
| Copyright Owner: | Copyright 2007 American Chemical Society |
| Copyright Statement: | This work is covered by copyright. Unless the document is being made available under a Creative Commons Licence, you must assume that re-use is limited to personal use and that permission from the copyright owner must be obtained for all other uses. If the document is available under a Creative Commons License (or other specified license) then refer to the Licence for details of permitted re-use. It is a condition of access that users recognise and abide by the legal requirements associated with these rights. If you believe that this work infringes copyright please provide details by email to qut.copyright@qut.edu.au |
| Deposited On: | 07 Mar 2007 00:00 |
| Last Modified: | 03 Mar 2024 15:21 |
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