Near-Infrared Spectroscopy of Stitchtite, Iowaite, Desautelsite and Arsenate Exchanged Takovite and Hydrotalcite
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Description
The hydrotalcite minerals stitchtite, iowaite and desautelsite together with the arsenate exchanged takovite and arsenate exchanged hydrotalcite have been studied using near-IR reflectance spectroscopy. Each mineral has its own characteristic NIR spectrum enabling recognition of the particular hydrotalcite. As such the technique has application in the field for the analysis and identification of hydrotalcites. Hydrotalcites have proven useful as an anion exchange material. Takovite and hydrotalcite were used to exchange carbonate anions by arsenate. Three Near–IR spectral regions are identified: (a) the high wavenumber region between 6400 and 7400 cm-1 attributed to the first overtone of the fundamental hydroxyl stretching mode (b) the 4800-5400 cm-1 region attributed to water combination modes of the hydroxyl fundamentals of water, and (c) the 4000-4800 cm-1 region attributed to the combination of the stretching and deformation modes of the MOH units of the hydrotalcites. NIR spectroscopy enables the separation of the hydroxyl bands of the water and M-OH units for the hydrotalcites. Compared with the NIR spectroscopy of the structural units of the hydrotalcites namely gibbsite and brucite, the bands are broad.
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ID Code: | 782 |
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Item Type: | Contribution to Journal (Journal Article) |
Refereed: | Yes |
Measurements or Duration: | 6 pages |
Keywords: | Desautelsite, Hydrotalcite, Iowaite, Near-IR Spectroscopy, Stitchite, Takovite |
DOI: | 10.1016/j.saa.2004.03.011 |
ISSN: | 1386-1425 |
Pure ID: | 34291128 |
Divisions: | Past > QUT Faculties & Divisions > Faculty of Science and Technology Past > QUT Faculties & Divisions > Science & Engineering Faculty Current > Research Centres > Australian Research Centre for Aerospace Automation |
Copyright Owner: | Consult author(s) regarding copyright matters |
Copyright Statement: | This work is covered by copyright. Unless the document is being made available under a Creative Commons Licence, you must assume that re-use is limited to personal use and that permission from the copyright owner must be obtained for all other uses. If the document is available under a Creative Commons License (or other specified license) then refer to the Licence for details of permitted re-use. It is a condition of access that users recognise and abide by the legal requirements associated with these rights. If you believe that this work infringes copyright please provide details by email to qut.copyright@qut.edu.au |
Deposited On: | 08 Mar 2005 00:00 |
Last Modified: | 03 Mar 2024 06:37 |
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