Infrared Spectroscopy of Organoclays Synthesized with the Surfactant Octadecyltrimethylammonium Bormide

, , , & (2005) Infrared Spectroscopy of Organoclays Synthesized with the Surfactant Octadecyltrimethylammonium Bormide. Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy, 61(3), pp. 515-525.

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Description

Infrared spectroscopy using a smart endurance single bounce diamond ATR cell has been used to study the changes in the spectra of the surfactant octadecyltrimethylammonium bromide upon intercalation into a sodium montmorillonite. The wavenumbers of bands attributed to CH stretching and bending vibrations in general decrease as the concentration of the surfactant measured in terms of the cation exchange capacity (CEC) up to 1.0 CEC. After this point the bands increase approaching a value the same as that of the surfactant. Significant changes occur in the HCH deformation modes of the methyl groups of the surfactant. These changes are attributed to the methyl groups locking into the siloxane surface of the montmorillonite. Such a concept is supported by changes in the SiO stretching bands of the montmorillonite siloxane surface

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123 citations in Scopus
109 citations in Web of Science®
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ID Code: 787
Item Type: Contribution to Journal (Journal Article)
Refereed: Yes
ORCID iD:
Xi, Yunfeiorcid.org/0000-0003-2924-9494
Measurements or Duration: 11 pages
Keywords: Infrared Spectroscopy, Montmorillonite, Octadecyltrimethylammonium Bromide, Surfactant
DOI: 10.1016/j.saa.2004.05.001
ISSN: 1386-1425
Pure ID: 34292005
Divisions: Past > QUT Faculties & Divisions > Faculty of Science and Technology
Past > QUT Faculties & Divisions > Science & Engineering Faculty
Current > Research Centres > Australian Research Centre for Aerospace Automation
Copyright Owner: Consult author(s) regarding copyright matters
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Deposited On: 14 Mar 2005 00:00
Last Modified: 29 Jul 2024 22:04