Infrared Spectroscopy of Organoclays Synthesized with the Surfactant Octadecyltrimethylammonium Bormide
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Description
Infrared spectroscopy using a smart endurance single bounce diamond ATR cell has been used to study the changes in the spectra of the surfactant octadecyltrimethylammonium bromide upon intercalation into a sodium montmorillonite. The wavenumbers of bands attributed to CH stretching and bending vibrations in general decrease as the concentration of the surfactant measured in terms of the cation exchange capacity (CEC) up to 1.0 CEC. After this point the bands increase approaching a value the same as that of the surfactant. Significant changes occur in the HCH deformation modes of the methyl groups of the surfactant. These changes are attributed to the methyl groups locking into the siloxane surface of the montmorillonite. Such a concept is supported by changes in the SiO stretching bands of the montmorillonite siloxane surface
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ID Code: | 787 | ||
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Item Type: | Contribution to Journal (Journal Article) | ||
Refereed: | Yes | ||
ORCID iD: |
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Measurements or Duration: | 11 pages | ||
Keywords: | Infrared Spectroscopy, Montmorillonite, Octadecyltrimethylammonium Bromide, Surfactant | ||
DOI: | 10.1016/j.saa.2004.05.001 | ||
ISSN: | 1386-1425 | ||
Pure ID: | 34292005 | ||
Divisions: | Past > QUT Faculties & Divisions > Faculty of Science and Technology Past > QUT Faculties & Divisions > Science & Engineering Faculty Current > Research Centres > Australian Research Centre for Aerospace Automation |
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Copyright Owner: | Consult author(s) regarding copyright matters | ||
Copyright Statement: | This work is covered by copyright. Unless the document is being made available under a Creative Commons Licence, you must assume that re-use is limited to personal use and that permission from the copyright owner must be obtained for all other uses. If the document is available under a Creative Commons License (or other specified license) then refer to the Licence for details of permitted re-use. It is a condition of access that users recognise and abide by the legal requirements associated with these rights. If you believe that this work infringes copyright please provide details by email to qut.copyright@qut.edu.au | ||
Deposited On: | 14 Mar 2005 00:00 | ||
Last Modified: | 29 Jul 2024 22:04 |
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