Facile two-step construction of a novel tetrathiamacrotricycle
Description
The reactions of [Os(CO)(CA)(PPh3)3] (A = O, S) with 4,7,10-trithiatrideca-2,11-diyne provide cyclopentadienone and cyclopentadienethione complexes, the latter affording a novel polythioether macrotricyclic ligand on subsequent treatment with dimethylacetylenedicarboxylate.
Impact and interest:
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| ID Code: | 9071 |
|---|---|
| Item Type: | Contribution to Journal (Journal Article) |
| Refereed: | Yes |
| Measurements or Duration: | 3 pages |
| DOI: | 10.1021/om040126v |
| ISSN: | 0276-7333 |
| Pure ID: | 34310892 |
| Divisions: | Past > QUT Faculties & Divisions > Faculty of Science and Technology Past > Schools > School of Physical & Chemical Sciences |
| Copyright Owner: | Consult author(s) regarding copyright matters |
| Copyright Statement: | This work is covered by copyright. Unless the document is being made available under a Creative Commons Licence, you must assume that re-use is limited to personal use and that permission from the copyright owner must be obtained for all other uses. If the document is available under a Creative Commons License (or other specified license) then refer to the Licence for details of permitted re-use. It is a condition of access that users recognise and abide by the legal requirements associated with these rights. If you believe that this work infringes copyright please provide details by email to qut.copyright@qut.edu.au |
| Deposited On: | 17 Aug 2007 00:00 |
| Last Modified: | 03 Mar 2024 06:53 |
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